1-Yes, open Disketch > Create new project > select CD and Case on Generic Paper > you will see tabs, click the one for "Standard CD case - Back".
2-Unfortuantely, the program does not offer an option to center image or text as you have described.
3-It may depend on the labels you have purchased. For additional information, you may need to check out this link: http://help.nchsoftware.com/help/en/disketch/win/concepts_stationery.html