Hi,
In this case you would need to contact National Australia Bank and request these details http://help.nchsoftware.com/help/en/moneyline/win/dlgaddfi.html
Once you have gathered that information, in MoneyLine, you need to follow these steps: click on the Accounts menu > Add Account > check the box "Enable online access account" > in the Online Access section, select for Financial Institution: Add New Financial Institution > enter the requested information > OK
Regards.