Hi kimber222,
to use your outlook.com email (I am using and outlook.com account on Windows 8 myself) you need to use the following settings:
Use SMTP to send email: Selected
SMTP mail host: smtp.live.com
Server requires authentication: Ticked
User Name: <your outlook.com email address>
Password: <your outlook.com password>
Use Secure Connection (SSL/TLS): Ticked
If server is down, attemtp to send directly: Ticked
Default reply email: <your outlook.com email address>